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Substituted 2-pyrazolines have been prepared by the reaction of chalcones with hydrazines in different media, benzenesulfonyl hydrazide and acyl-hydrazines. The pyrazolines are converted to benzoyl, benzyl derivatives, Mannich bases and to 4-bromopyrazoles. Chalcone dibromide is converted to isoxazole.read more
E A MOHAMED ,M EL MOBAYED ,A A ISMAIL ,G H SAYED ,
- 29 Jun 2011
- Volume Detail: VOLUME 11, NO2, JUN 1989
- Pages: 91
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Different dealuminated Y -zeolite samples were prepared by the removal of aluminium atoms from H4 Y-zeolite using the conventional method with chelating agent EDTA. The DTA of different dealuminated samples was investigated. The X-ray diffraction spectra of the prepared samples were also studied. The catalytic activity of these zeolite samples was tested using the cumene cracking reaction in a microcatalytic system. The results obtained revealed that the zeolite samples are thermally stable. The degree of crystallinity was nearly the same as the original, except for samples with a degree of dealumination higher than 40%. In the cumene cracking study, the reaction
M M SELIM ,E A SULTAN ,
- 29 Jun 2011
- Volume Detail: VOLUME 11, NO2, JUN 1989
- Pages: 96
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The rates of alkaline solvolysis of 3- chloropropionate ion at four different temperatures 30, 37, 43 and 57°C in water-tert. butyl alcohol have been measured. The rates of solvolysis were found to be second-order overall and first-order with respect to each 3chloropropionic acid and hydroxide ions concentrations. There is no simple correlation between the dielectric constant "D" and the rate constant "k". The addition of tert. butyl alcohol to water causes an increase of the rate in a non-linear form. The activation parameters Ea, Ll H, Ll S for the solvolysis reaction pass throug
M A MOUSA ,EL H M DIEFALLAH ,M M ABEDEL BADEI ,M M ASSEM ,
- 29 Jun 2011
- Volume Detail: VOLUME 11, NO2, JUN 1989
- Pages: 102
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Cobalt/aluminium mixed oxides of varying compositions (0.05 to 0.2 C0304:A120J) were prepared by impregnating finelly powdered poorly crystalline gama-alumina with different proportions of cobalt nitrate using a pore-filling method. The prepared solids were dried ilt 100°C then calcined at 450-900°C. The catalytic activities of different supported solids were determined using the catalytic oxidation of CO with 02 at 80- 300°C by these mixed oxides. The apparrent activation energies (D-E) of the catalytic reaction were determined for each catalyst from the data of first-order reaction rate constant (k) measured at different reaction temperatures for various solids precalcined at different temperatures.The results obtained revealed that the catalytic activity increases progressively by increasing the amount of cobalt o
G A EL SHOBAKY ,G A FAGAL ,NABIL H AMIN ,
- 29 Jun 2011
- Volume Detail: VOLUME 11, NO2, JUN 1989
- Pages: 107
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The reactivity of 4-(p-tolyl)-5,6,7,8- tetrabromo 1(2H) phthalazinone (I) which contains two reaction sites (C = a and C = N) was investigated for reaction with alkyl or aralkyl magnesium halide under Grignard reaction conditions. This work also deals with the synthesis of the chlorophthalazine (III) via the interaction of the titled phthalazinone with POC13/PCIs mixture, the chloro derivative having chlorine atom activated by heteryl moiety. Therefore nucleophilic substitution reaction took place readily with the chloro substrate. The structures assigned to the products are supported by IR and NMR spectra.read more
S A ESSAWY ,A M M F EISSA ,A A ELSAWY ,S G DONIA ,
- 29 Jun 2011
- Volume Detail: VOLUME 11, NO2, JUN 1989
- Pages: 111
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An indirect atomic absorption method is described for the determination of ammonia. The method is based on the reduction of silver ions with ammonia in presence of manganese (II) ions. The unconsumed silver, in solution, is determined by atomic absorption spectroscopy. A numh;;r of related factors have been studied and the procedure is employed for the determination of ammonia obtained from nitrogen containing compounds.read more
JAMIL ANWAR ,M MAKSHOOF ATTHAR ,M I FAROOQ ,
- 29 Jun 2011
- Volume Detail: VOLUME 11, NO2, JUN 1989
- Pages: 117
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A simple indirect spectrophotometric method is described for the microdetermination of sulphide. The method is based on the reduction of iron(III) by sulphide ions. The reduced iron(II) forms a red complex with 1,10-phenanthroline. Absorbance of the red complex is measured at 510 nm. The method is found capable of determining sulphide in the range 0.1-05 f.Lg/mI. Effect of a number of concerned parameters and interferences due to other ions have been checked.read more
JAMIL ANWAR ,TAFHEEM AHMAD AWAN ,
- 29 Jun 2011
- Volume Detail: VOLUME 11, NO2, JUN 1989
- Pages: 121
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A flow-injection procedure for the indirect determination of a primal)' bile acid (cholyl glyci.1e) using immobilized 7a-hydroxysteroid dehydrogenase and co-immobilized bacterial luciferase and oxidoreductase is described. The linear range is lxlO·6_1xlO,3 M cholyl glycine. The reproducibility is less than 3.4% (n =5) and the sample throughput is 60 m-l.read more
A NABI ,P J WORSFOLD ,
- 29 Jun 2011
- Volume Detail: VOLUME 11, NO2, JUN 1989
- Pages: 127
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The reaction of terphthalic acid with peroxodisulphate with and without the presence of Agtl) catalyst has been studied kinetically. The reaction rates have been found to show first-order dependence on peroxodisulphate concentration. The reaction products have been identified and a free radical mechanism is proposed.read more
G M KHAN ,M J IQBAL ,
- 29 Jun 2011
- Volume Detail: VOLUME 11, NO2, JUN 1989
- Pages: 130
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Distribution coefficients have been measured for the partition of metal ions. Th(IV). Mg(I1), Ni(II) and Cu(II) between cation exchange resin of Dower HCR-S and water-. water - organic solvent - HCI solutions. The effect of variation in concentration of isopropanol. acetone and dioxane on the distribution coefficients of the metal ions have been studied. The effect of change in the acidity of the medium has also been studied by vaIying (HCl). The possibilities of several useful separations has been suggested and the distribution coefficient data was calculated.read more
F H KAMAL ,A M SALEEM ,E A HASSAN ,A S ABOUL MAGD ,
- 29 Jun 2011
- Volume Detail: VOLUME 11, NO2, JUN 1989
- Pages: 135
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